| 06/09/1964 | KFC Malinois – AS Oostende | 2 – 0 | |
| 13/09/1964 | KFC Turnhout – KFC Malinois | 1 – 1 | |
| 20/09/1964 | KFC Malinois – Patro Eisden | 2 – 0 | |
| 27/09/1964 | KSV Waregem – KFC Malinois | 1 – 1 | |
| 11/10/1964 | KFC Malinois – R. Charleroi SC | 3 – 2 | |
| 18/10/1964 | KSC Eendracht Aalst – KFC Malinois | 2 – 1 | |
| 25/10/1964 | KFC Malinois – UR Namur | 4 – 3 | |
| 08/11/1964 | RCS Verviétois – KFC Malinois | 1 – 0 | |
| 15/11/1964 | R. Crossing Club Molenbeek – KFC Malinois | 2 – 3 | |
| 22/11/1964 | KFC Malinois – ROC Charleroi | 0 – 0 | |
| 29/11/1964 | R. Racing White – KFC Malinois | 0 – 1 | |
| 06/12/1964 | KFC Malinois – K. Sint-Niklaasse SK | 7 – 2 | |
| 13/12/1964 | KSV Waterschei THOR Genk – KFC Malinois | 3 – 1 | grootste verlies |
| 20/12/1964 | KFC Malinois – K. Boom FC | 0 – 1 | |
| 10/01/1965 | AS Oostende – KFC Malinois | 1 – 1 | |
| 17/01/1965 | KFC Malinois – KFC Turnhout | 2 – 0 | |
| 24/01/1965 | Patro Eisden – KFC Malinois | 1 – 1 | |
| 31/01/1965 | KFC Malinois – KSV Waregem | 1 – 0 | |
| 07/02/1965 | R. Charleroi SC – KFC Malinois | 1 – 6 | |
| 14/02/1965 | KFC Malinois – KSC Eendracht Aalst | 3 – 0 | |
| 21/02/1965 | UR Namur – KFC Malinois | 2 – 0 | grootste verlies |
| 28/02/1965 | KFC Herentals – KFC Malinois | 2 – 1 | |
| 07/03/1965 | KFC Malinois – RCS Verviétois | 6 – 0 | grootste zege |
| 14/03/1965 | KFC Malinois – R. Crossing Club Molenbeek | 3 – 1 | |
| 21/03/1965 | ROC Charleroi – KFC Malinois | 1 – 4 | |
| 28/03/1965 | KFC Malinois – R. Racing White | 1 – 2 | |
| 04/04/1965 | K. Sint-Niklaasse SK – KFC Malinois | 0 – 0 | |
| 11/04/1965 | KFC Malinois – KSV Waterschei THOR Genk | 3 – 1 | |
| 09/05/1965 | KFC Malinois – KFC Herentals | 5 – 1 | |
| 16/05/1965 | K. Boom FC – KFC Malinois | 2 – 5 |
| eindklassement tweede nationale | aantal | winst | gelijk | verlies | goals+ | goals- | ptn | |
| 1 | ROYAL RACING WHITE | 30 | 17 | 7 | 6 | 47 | 18 | 41 |
| 2 | KONINKLIJKE FOOTBALL CLUB MALINOIS | 30 | 17 | 6 | 7 | 68 | 33 | 40 |
| 3 | Koninklijke Sint-Niklaasse Sportkring | 30 | 14 | 7 | 9 | 48 | 43 | 35 |
| 4 | Royal Olympic Club de Charleroi | 30 | 14 | 4 | 12 | 48 | 45 | 32 |
| 5 | Koninklijke Sportvereniging Waterschei THOR Genk | 30 | 13 | 6 | 11 | 49 | 42 | 32 |
| 6 | Atletische Sportvereniging Oostende | 30 | 12 | 8 | 10 | 58 | 39 | 32 |
| 7 | Royal Crossing Club Molenbeek | 30 | 13 | 5 | 12 | 48 | 40 | 31 |
| 8 | Koninklijke Sportvereniging Waregem | 30 | 12 | 7 | 11 | 51 | 45 | 31 |
| 9 | Koninklijke Football Club Turnhout | 30 | 11 | 9 | 10 | 40 | 40 | 31 |
| 10 | Union Royale Namur | 30 | 13 | 2 | 15 | 58 | 68 | 28 |
| 11 | Patro Eisden | 30 | 11 | 6 | 13 | 47 | 58 | 28 |
| 12 | Royal Charleroi Sporting Club | 30 | 10 | 8 | 12 | 41 | 55 | 28 |
| 13 | Royal Club Sportif Verviétois | 30 | 9 | 9 | 12 | 47 | 56 | 27 |
| 14 | Koninklijke Football Club Herentals | 30 | 11 | 4 | 15 | 48 | 65 | 26 |
| 15 | Koninklijke Sportclub Eendracht Aalst | 30 | 6 | 8 | 16 | 33 | 55 | 20 |
| 16 | Koninklijke Boom Football Club | 30 | 6 | 6 | 18 | 26 | 55 | 18 |
Opmerking: KSC Eendracht Aalst degradeerde naar vierde nationale!